Study of Optical Properties of Cd(1-x)SO4:XDy3+ Yellow Emitting Phosphor for W-LED Applications

Authors

  • Suhas T. Taide Jawaharlal Darda Institute of Engineering & Technology Yavatmal, Maharashtra, India Author

DOI:

https://doi.org/10.32628/IJSRST25125125

Abstract

This article report Cd(1-x)SO4:XDy3+ phosphor which were synthesized using recrystalization method, Crystal structure and phase formation of the product was identified by powder XRD technique and partical morphology was studied by FE-SEM .According to the results of the PL analysis carried out by the Hitachi F-7000 fluorescence spectrophotometer. The luminescence decay curves of CdSO4(1-x):xDy3+ phosphors for utilizing excitation wavelengths of 350nm and emission wavelengths of 575 nm that were recorded by and HITACHI F-7000 Spectroflurophotometer. It has been shown that the decay time is around 0.75 ms The photoluminescence (PL) spectra were investigated under 350 nm (UV) excitation, two emission peaks were obtained one at 483 nm, which falls under the blue region, and the other at 575 nm, which falls under the bright yellow region. These two emission peaks correspond to the 4F9/2 to 6H15/2 and 4F9/2 to 6H13/2 transitions, respectively. We suggest that the CdSO4:Dy3+ can be employed as an excellent luminescent material with ultraviolet radiation as an excitation source for a variety of optical applications based on its optical properties. White light for WLED applications can be produced by a special phase doping of Dy3+ species in the host material with yellow and blue emission.

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References

Gao, M.; Li, K.; Yan, Y.; Xin, S.; Dai, H.; Zhu, G.; Wang, C. Novel thermally robust warm white light emitting phosphorCa18Li3Y(PO4)14:Dy3+ : Synthesis, crystal structure and luminescence property investigation. J. Mol. Struct. 2021, 1228, 129471, DOI: https://doi.org/10.1016/j.molstruc.2020.129471

Yu, M.; Zhang, W.; Yan, G.; Dai, S.; Qiu, Z.; Zhang, L. Warm white emission property of Ca2Sr(PO4)2:Dy3+ phosphors with red compensation byEu3+ co-doping. Ceram. Int. 2018, 44, 2563–2567, DOI: https://doi.org/10.1016/j.ceramint.2017.11.012

Cao, R.; Zheng, Y.; Chen, T.; Lan, B.; Li, L.; Zhong, Q.; Nie, S.; Wang, J. Synthesis and tunable emission from yellow-green to red-orange of Ca3MgSi2O8: Eu3+, Dy3+ phosphor. J. Mol. Struct. 2022, 1262, 133008, DOI: https://doi.org/10.1016/j.molstruc.2022.133008

Pradhan, M.K.; Rao, T.L.; Dash, S. Dy3+ Activated Nearly White Emitting NaCdPO4 as Potential Phosphors for Solid State Light Applications. J. Electron. Mater. 2020, 49, 2463–2470. DOI: https://doi.org/10.1007/s11664-020-07954-w

Yu, M.; Xu, X.; Zhang, W.; Chen, X.; Zhang, P.; Huang, Y. The effect of Sm3+ co-doping on the luminescence properties of Ca2•85Li0•15 (PO4)1•85(SO4)0.15: Dy3+ white-emitting phosphors. J. Alloys Compd. 2020, 817, 152761, DOI: https://doi.org/10.1016/j.jallcom.2019.152761

Nagpure, I.M.; Pawade, V.B.; Dhoble, S.J. Combustion synthesis of Na2Sr(PO4)F: Dy3+ white light emitting phosphor. Luminescence 2010, 25, 9–13, DOI: https://doi.org/10.1002/bio.1132

Duragkar, A.; Kohale, R.L.; Dhoble, N.S.; Dhoble, S.J. Tunable luminescence of Eu3+, Sm3+ and Dy3+ doped Na2CaMg(PO4)2 phosphor for optical applications. J. Mol. Struct. 2020, 1199, 126969, DOI: https://doi.org/10.1016/j.molstruc.2019.126969

Khajuria, P.; Manhas, M.; Bedyal, A.K.; Vij, A.; Swart, H.C.; Kumar, V. Structural and spectral investigation of a near-UV-converted LiSrP3O9:Dy3+ spectral investigation of a near-UV-converted J. Mater. Sci. Mater. Electron. 2022, 33, 6031–6042, DOI: https://doi.org/10.1007/s10854-022-07782-0

Ci, Z.; Sun, Q.; Qin, S.; Sun, M.; Jiang, X.; Zhang, X.; Wang, Y. Warm white light generation from a single phase Dy3+ doped Mg2Al4Si5O18 phosphor for white UV-LEDs. Phy. Chem. Chem. Phy. 2014, 16, 11597– 11602.

Hakeem, D.A.; Pi, J.W.; Kim, S.W.; Park, K. New Y2LuCaAl2SiO12:Ln (Ln = Ce3+, Eu3+ and Tb3+) phosphors for white LED applications. Inorg. Chem. Front. 2018, 5, 1336-1345, DOI: https://doi.org/10.1039/C8QI00111A

Ci, Z.; Sun, Q.; Qin, S.; Sun, M.; Jiang, X.; Zhang, X.; Wang, Y. Warm white light generation from a single phase Dy3+ doped Mg2Al4Si5O18 phosphor for white UV-LEDs. Phy. Chem. Chem. Phy. 2014, 16, 11597– 11602. DOI: https://doi.org/10.1039/C4CP00357H

Krishnapriya, T.; Mohan P.R.; Jose, A.; Jose, J.R.; Joseph, C.; Biju, P.R. Synthesis and luminescence characteristics of Na6Ca(1-X)P2O9:XDy3+ phosphor for outdoor lighting applications. Mater. Chem. Phys. 2022, 280, 125827. DOI: https://doi.org/10.1016/j.matchemphys.2022.125827

R. M. Yerojwar, N. S. Kokode, C. M. Nandanwar, Synthesis and Photoluminescence characterization of ZnAl12O19:Sm3+ Phosphor for W-LED, International Journal of Scientific Research in Science and Technology (IJSRST), 9 (3), 811 (2022). DOI: https://doi.org/10.32628/IJSRST2293159

R. M. Yerojwar, N. S. Kokode, C. M. Nandanwar, Luminescence Properties of Rare Earth Sm3+ Doped Ca2Mg2Al28O46 Phosphor for white light emitting diode, International Journal of Scientific Research and Innovative Studies (IJSRIS), 1(1), 135 (2022);

A. K. Vishwakarma, M. Jayasimhadri, Pure orange color emitting Sm3+ doped BaNb2O6 phosphor for solid-state lighting applications, Journal of Luminescence, 176, 112 (2016). DOI: https://doi.org/10.1016/j.jlumin.2016.03.025

C. M. Nandanwar, N. S. Kokode, A. N. Yerpude, S. J. Dhoble, Luminescence properties of LaPO4:RE (RE = Dy3+, Eu3+, Sm3+) orthophosphate phosphor for n-UV solid-state lighting prepared by wet chemical synthesis, Journal of Materials Science: Materials in Electronics, 34, 707 (2023). DOI: https://doi.org/10.1007/s10854-023-10119-0

C. Yue, X. He, Y. Pu, D. Zhu, Synthesis and properties of a yellowish-green Sr3La(AlO)3(BO3)4:Tb3+ phosphor with a high thermal stability, Journal of Luminescence, 249, 119046 (2022). DOI: https://doi.org/10.1016/j.jlumin.2022.119046

S. Kaur, A. S. Rao, M. Jayasimhadri, Spectroscopic and Photoluminescence Characteristics of Sm3+ doped Calcium Aluminozincate Phosphor for Applications in w-LEDs, Ceramics International, 43, 7401 (2017). DOI: https://doi.org/10.1016/j.ceramint.2017.02.129

C. M. Nandanwar, N. S. Kokode, A. N. Yerpude, S. J. Dhoble, Effect of dopant concentration on luminescence properties of a Ba3(PO4)2: RE (RE= Sm3+, Eu3+, Dy3+) phosphor for solid-state lighting, Chemical Data Collections 43, 100979 (2023). DOI: https://doi.org/10.1016/j.cdc.2022.100979

C. M. Nandanwar, N. S. Kokode, A. N. Yerpude, S. J. Dhoble, Luminescence properties of BiPO4:Ln (Ln = Dy3+, Tb3+ and Sm3+) orthophosphate phosphors for near-UV-based solid-state lighting, Bulletin of Materials Science, 46, 51 (2023). DOI: https://doi.org/10.1007/s12034-023-02900-y

C. C. Lin, R. S. Liu, Advances in Phosphors for Light-emitting Diodes, The Journal of Physical Chemistry Letters 2, 1268 (2011). DOI: https://doi.org/10.1021/jz2002452

Z. H. Ju, R. P. Wei, J. X. Ma, C. R. Pang, W. S. Liu, A novel orange emissive phosphor SrWO4:Sm3+ for white light-emitting diodes, Journal of Alloys and Compounds, 507, 133 (2010). DOI: https://doi.org/10.1016/j.jallcom.2010.07.138

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Published

20-09-2025

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Research Articles

How to Cite

[1]
Suhas T. Taide, Tran., “Study of Optical Properties of Cd(1-x)SO4:XDy3+ Yellow Emitting Phosphor for W-LED Applications”, Int J Sci Res Sci & Technol, vol. 12, no. 5, pp. 215–221, Sep. 2025, doi: 10.32628/IJSRST25125125.