Synthesis, Characterization of Macrocyclic Complexes of 3D Series Transition Metal Ions
DOI:
https://doi.org/10.32628/IJSRST251263204Keywords:
Macrocyclic complex, 1,3-dicarbonyl-phenyl-dihydrazideAbstract
Transition metal macrocyclic complexes have been extensively studied by researchers in search of designing new chemical agents because of their excellent biological activities, including antimicrobial, antioxidant and anticarcinogenic. Presence of metal ions accelerates the drug action and efficiency of organic therapeutic agents. Transition metal complexes based on hydrazides of carboxylic acids have displayed wide range of biological and pharmaceutical activities because of the formation of –CONH- linkage which is used as building unit for peptides formation from amino acids in biological systems. It also gives higher stability to the molecules because of the presence of a chelatophore group of donor atoms in the coordination sphere. In this present paper we studied about synthesis and characterization of macrocyclic complex of 3D series transition metal ions.
Downloads
References
Zhou C, Wang Y (2012) Recent Researches in Triazole Compounds as Medicinal Drugs. Current Medicinal Chemistry; 19(2):239-280 DOI: https://doi.org/10.2174/092986712803414213
Andrei K Yudin (2015) Macrocycles: lessons from the distant past, recent developments, and future directions. Chemical Science; (1):1-844 DOI: https://doi.org/10.1039/C4SC03089C
Chandra S, Pundir M (2008) Spectroscopic characterization of chromium(III), manganese(II) and nickel(II) complexes with a nitrogen donor tetradentate, 12-membered azamacrocyclic ligand. Spectrochim Acta A; 69 (1):1–7. DOI: https://doi.org/10.1016/j.saa.2007.02.019
Kumar G , Devi S , Johari R , Kumar D(2012) Synthesis, spectral characterization and antimicrobial evaluation of Schiff base Cr (III), Mn (III) and Fe (III) macrocyclic complexes. Eur J Med Chem; 52:269-274 DOI: https://doi.org/10.1016/j.ejmech.2012.03.025
Niasari M S, Daver F (2006) New 14-membered octaazamacrocyclic complexes: Synthesis, spectral, antibacterial and antifungal studies.Inorg Chem Commun; 9:175-179
Rathi P, Singh D P (2015) Antimicrobial and antioxidant activity evaluation of Co(II), Ni(II), Cu(II) and Zn(II) complexes with 15-thia-3,4,9,10-tetraazabicyclo [10.2.1] pentadeca-1 (14),2,10,12-tetraene-5,8-dione. Spectrochim Acta Mol Biomol Spectrosc; 136:381–387 DOI: https://doi.org/10.1016/j.saa.2014.09.044
Forghieri, F., Preti, C., Tosi, G., & Zonnini, P. (1983). Preparation and pharmacological study of some noval metal complexes. Aust. J. Chem, 36, 1125-1125. DOI: https://doi.org/10.1071/CH9831125
Kucukguzel S G, Rollas S, Kucukguzel I, Kiraz M(1999) Synthesis and antimycobacterial activity of some coupling products from 4-aminobenzoic acid hydrazones. Eur J Med Chem; 34(12):1093-1100. DOI: https://doi.org/10.1016/S0223-5234(99)00129-4
Zhang S, Sherry A D(2003) Physical characteristics of lanthanide complexes that act as magnetization transfer (MT) contrast agents. J Solid State Chem; 171(1-2): 38-43. DOI: https://doi.org/10.1016/S0022-4596(02)00143-3
Prasad R N, Mathur M, Upadhyay A(2007) Synthesis and spectroscopic studies of Cr III, Fe III and Co II complexes of hexaazamacrocycles. J Indian Chem Soc; 84(12):1202- 1204
Avaji, P. G., Kumar, C. V., Patil, S. A., Shivananda, K. N., & Nagaraju, C. (2009). Synthesis, spectral characterization, in-vitro microbiological evaluation and cytotoxic activities of novel macrocyclic bis hydrazone. European journal of medicinal chemistry, 44(9), 3552-3559. DOI: https://doi.org/10.1016/j.ejmech.2009.03.032
Smith, I. (Ed.). (2013).Chromatography. Elsevier.
Geary, W. J. (1971). The use of conductivity measurements in organic solvents for the characterisation of coordination compounds. Coordination Chemistry Reviews, 7(1), 81- 122. DOI: https://doi.org/10.1016/S0010-8545(00)80009-0
Srinivasan, S., Athappan, P., & Rajagopal, G. (2001). Synthesis, spectral and redox properties of metal complexes of macrocyclic tetraaza chiral Schiff bases. Transition Metal Chemistry, 26(4-5), 588-593. DOI: https://doi.org/10.1023/A:1011007429295
Zeng, Q., Sun, J., Gou, S., Zhou, K., Fang, J., & Chen, H. (1998). Synthesis and spectroscopic studies of dinuclear copper (II) complexes with new pendant-armed macrocyclic ligands. Transition Metal Chemistry, 23(4), 371-373. DOI: https://doi.org/10.1023/A:1006994300484
Lodeiro, C., Bastida, R., Bértolo, E., Macías, A., & Rodríguez, A. (2003). Synthesis and characterisation of four novel N x O y-Schiff-base macrocyclic ligands and their metal complexes. Transition metal chemistry, 28(4), 388-394. DOI: https://doi.org/10.1023/A:1023672629805
Kantekin, H., Ocak, Ü., Gök, Y., & Acar, I. (2004). The synthesis and characterization of a novel vic-dioxime and its mononuclear complexes bearing an 18-membered 2 O 2 S 2 macro-cycle and their characteristics as extractants for transition metal ions. Journal of inclusion phenomena and macrocyclic chemistry, 48(3-4), 95-101. DOI: https://doi.org/10.1023/B:JIPH.0000022530.02686.cf
Prasad, R. N., Mathur, M., & Upadhyay, A. (2007). Synthesis and spectroscopic studies of Cr (III), Fe (III) and Co (II) complexes of hexaazamacrocycles. Journal of the Indian Chemical Society, 84(12), 1202-1204.
Costamagna, J., Ferraudi, G., Villagran, M., & Wolcan, E. (2000). Ligand luminescence and photoinduced charge separation in bis (naphthalene) substituted fourteen-membered tetraazamacrocyclic complexes of Cu II and Ni II. Journal of the Chemical Society, Dalton Transactions, (15), 2631-2637. DOI: https://doi.org/10.1039/b002829k
Chandra, S., & Gupta, L. K. (2004). Spectroscopic characterization of tetradentate macrocyclic ligand: it’s transition metal complexes. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 60(12), 2767-2774. DOI: https://doi.org/10.1016/j.saa.2004.01.015
Gliemann, G. (1978). K. Nakamoto: Infrared and Raman Spectra of Inorganic and Coordination Compounds. John Wiley and Sons, New York, Chichester, Brisbane, Toronto 1978. 3. Aufl., XV, 448 Seiten mit 109 Abbildungen und 95 Tabellen. Preis: 31, 15. Berichte der Bunsengesellschaft für physikalische Chemie, 82(11), 1263-1263. DOI: https://doi.org/10.1002/bbpc.19780821138
Shakir, M., Nasman, O. S., & Varkey, S. P. (1996). Binuclear N 6 22-membered macrocyclic transition metal complexes: synthesis and characterization. Polyhedron, 15(2), 309-314. DOI: https://doi.org/10.1016/0277-5387(95)00189-Y
Shakir, M., Islam, K. S., Mohamed, A. K., Shagufta, M., & Hasan, S. S. (1999). Macrocyclic complexes of transition metals with divalent polyaza units. Transition Metal Chemistry, 24(5), 577-580.. DOI: https://doi.org/10.1023/A:1006900222831
Singh, M., & Nayan, R. (1997). Copper (II) Complexes with Macrocyclic Ligands Derived from 1, 2-Diaminoethane and Some Chlorocarbons. Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry, 27(4), 619-637. DOI: https://doi.org/10.1080/00945719708000214
Aqra, F. M. (1999). New macrocyclic complexes containing amide, imine and secondary amine functions. Transition Metal Chemistry, 24(3), 337-339. DOI: https://doi.org/10.1023/A:1006962812246
Chandra, S., & Kumar, R. (2004). Synthesis and spectral studies on mononuclear complexes of chromium (III) and manganese (II) with 12-membered tetradentate N2O2, N2S2 and N4 donor macrocyclic ligands. Transition metal chemistry, 29(3), 269-275; Chandra, S. (2004). Spectroscopic, redox and biological activities of transition metal complexes with ons donor macrocyclic ligand derived from semicarbazide and thiodiglycolic acid. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 60(8), 2153-2162.
Shakir, M., Varkey, S. P., & Hameed, P. S. (1993). Divalent, cobalt, nickel, copper and zinc complexes of tetraaza macrocycles bearing polyamide groups: synthesis and characterization. Polyhedron, 12(23), 2775-2780. DOI: https://doi.org/10.1016/S0277-5387(00)80058-3
Chandra, S., Gupta, N., & Gupta, L. K. (2004). Synthesis and EPR Spectral Studies of Mono-and Binuclear Cobalt (II) and Nickel (II) Complexes with New 20‐Membered Dithiatetraazamacrocyclic [N4S2] Ligand. Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry, 34(5), 919-927. DOI: https://doi.org/10.1081/SIM-120037516
Mohamed, A. K., Islam, K. S., Hasan, S. S., & Shakir, M. (1999). Metal ion directed synthesis of 14–16 membered tetraimine macrocyclic complexes. Transition Metal Chemistry, 24(2), 198-201. DOI: https://doi.org/10.1023/A:1006903000739
Pavia, D. L., Lampman, G. M., Kriz, G. S., & Vyvyan, J. A. (2008). Introduction to spectroscopy. Cengage Learning.
Chandra, S., & Pundir, M. (2007). Spectral studies of cobalt (II) complexes of 12- membered macrocyclic ligands having thiosemicarbazone moieties. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 68(3), 883-890.; DOI: https://doi.org/10.1016/j.saa.2006.12.074
Figgis, B. N., & Lewis, J. (1964). The magnetic properties of transition metal complexes. Progress in Inorganic Chemistry, Volume 6, 37-239. DOI: https://doi.org/10.1002/9780470166079.ch2
Lever, A. B. P. (1984). Electronic spectra of dn ions. Inorganic electronic spectroscopy, 2, 376-611.
Shukla, D., Gupta, L. K., & Chandra, S. (2008). Spectroscopic studies on chromium (III), manganese (II), cobalt (II), nickel (II) and copper (II) complexes with hexadentate nitrogen–sulfur donor [N 2 S 4] macrocyclic ligand. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 71(3), 746-750. Chandra, S., & Gupta, L. K. (2005). Spectroscopic approach in characterization of chromium (III), manganese (II), iron (III) and copper (II) complexes with a nitrogen donor tetradentate, 14-membered azamacrocyclic ligand. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 61(9), 2139-2144. DOI: https://doi.org/10.1016/j.saa.2004.06.060
Jörgensen, K. C. (1956). Complexes of the 4d-and 5d-Groups. I. Crystal Field Spectra of Rhodium (III) and Iridium (III). Acta. Chem. Scand, 10, 500. DOI: https://doi.org/10.3891/acta.chem.scand.10-0500
Saraswat, R., & Rana, V. B. (1998). Trivalent metal chelates of macrocycle derived from dihydrazide and aromatic diketone. Journal of the Indian Chemical Society, 75(9), 493- 495.
Prasad, R. N., & Mathur, M. (2002). Synthesis characterization of Cr (III), Fe (III), Co (II), Ni (II), Cu (II) and Zn (II) complexes of 2, 12-dimethyl-3-13-di-n-propyl-l, 4, 11, 14-tetraazacycloeicosa-1, 13, 11, 13-tetraene. Journal of the Serbian Chemical Society, 67(12), 825-832. DOI: https://doi.org/10.2298/JSC0212825P
Chandra, S. (2004). Spectroscopic, redox and biological activities of transition metal complexes with ons donor macrocyclic ligand derived from semicarbazide and thiodiglycolic acid. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 60(8), 2153-2162. DOI: https://doi.org/10.1016/j.saa.2003.09.027
Sathyanarayana, D. N. (2001). Electronic absorption spectroscopy and related techniques. Universities Press.
Kumar, U., & Chandra, S. (2010). Biological Active Cobalt (II) and Nickel (II) Complexes of 12-Membered Hexaaza [N 6] Macrocyclic Ligand Synthetic and Spectroscopic Aspects. Journal of Chemistry, 7(4), 1238-1245. DOI: https://doi.org/10.1155/2010/518723
Dunn, T. M. (1960). The visible and ultraviolet spectra of complex compounds in modern coordination chemistry. Interscience, New York.
Rana, V. B., Singh, D. P., Singh, M. P., & Teotia, M. P. (1981). Divalent nickel, cobalt and copper complexes of a tetradentate N6 macrocyclic ligand. Transition Metal Chemistry, 6(1), 36-39. DOI: https://doi.org/10.1007/BF01143465
Hathaway, B. J., and P. G. Hodgson. "Copper-ligand bond-lengths in axial complexes of the copper (II) ion." Journal of Inorganic and Nuclear Chemistry 35.12 (1973): 4071- 4081. DOI: https://doi.org/10.1016/0022-1902(73)80395-1
Gudasi, K. B., Patil, S. A., Vadavi, R. S., Shenoy, R. V., & Patil, M. S. (2006). Synthesis and spectral studies of Cu (II), Ni (II), Co (II), Mn (II) Zn (II) and Cd (II) complexes of a new macroacyclic ligand N, N'-bis (2-benzothiazolyl)-2, 6-pyridinedicarboxamide. Journal-serbian chemical society, 71(5), 529. DOI: https://doi.org/10.2298/JSC0605529G
Billing, D. E., & Hathaway, B. J. (1969). Single‐Crystal ESR Spectrum of Bis (ethylenediamine) Copper (II) Nitrate; the Calculation of Molecular g Values for Rhombic Symmetry from Data on Crystals Containing Inequivalent Orientations. The Journal of Chemical Physics, 50(3), 1476-1477. DOI: https://doi.org/10.1063/1.1671216
El-Boraey, H. A., & El-Gammal, O. A. (2015). New 15-membered tetraaza (N 4) macrocyclic ligand and its transition metal complexes: Spectral, magnetic, thermal and anticancer activity. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 138, 553-562. DOI: https://doi.org/10.1016/j.saa.2014.11.015
Downloads
Published
Issue
Section
License
Copyright (c) 2025 International Journal of Scientific Research in Science and Technology
This work is licensed under a Creative Commons Attribution 4.0 International License.
https://creativecommons.org/licenses/by/4.0
